Rhodium(iii)-catalyzed ortho-olefination of aryl phosphonates.

نویسندگان

  • Bathoju Chandra Chary
  • Sunggak Kim
چکیده

Rhodium(iii)-catalyzed C-H olefination of aryl phosphonic esters is reported for the first time. In this mild and efficient process, the phosphonic ester group is utilized successfully as a new directing group. In addition, mono-olefination for aryl phosphonates is observed using a phosphonic diamide directing group.

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عنوان ژورنال:
  • Organic & biomolecular chemistry

دوره 11 40  شماره 

صفحات  -

تاریخ انتشار 2013